珠江三角洲不同成土母质发育水稻土镉活动性差异及其影响因素     

王佳鑫  侯青叶  叶丹君  杨忠芳  余涛 《现代地质》2023,37(1):197-207

随着我国经济社会的快速发展,土壤重金属的超标问题越来越突出,尤其是Cd。土壤Cd活动性受到各种因素的影响,但成土母质对土壤Cd活动性影响的研究成果还鲜有报道。以珠江三角洲为研究区,系统采集了由第四纪沉积物、酸性侵入岩和陆源碎屑岩3种不同成土母质发育形成的水稻土样品235件,查明了土壤理化特征,探讨了Cd全量及其活动态的影响因素。结果表明：不同成土母质发育形成的水稻土理化性质、Cd全量及其活动态的影响因素存在差异。第四纪沉积物发育形成的水稻土CaO、K₂O、Na₂O、TFe₂O₃、阳离子交换量(CEC)、pH、有机质、黏粒平均含量显著高于酸性侵入岩和陆源碎屑岩,Cd超标最为严重,不同方法提取的Cd活动态含量也最高;陆源碎屑岩发育形成的水稻土中Cd全量与土壤理化指标的相关性均强于其他两类成土母质;酸性侵入岩发育形成的水稻土中Cd全量与土壤理化指标的相关性较弱。Cd全量对其活动态含量有重要影响,此外,第四纪沉积物发育的水稻土中Cd活动态含量与pH、有机质和TFe₂O₃  相似文献   

内蒙古阿拉善地区绿色戈壁玛瑙的宝石学特征与致色成因研究          下载免费PDF全文

张润清  杜景红 《岩石矿物学杂志》2023,42(1):104-112

内蒙古阿拉善地区经历数亿年的地质活动,产出颜色丰富且结构致密的戈壁玛瑙。通过常规宝石学测试、偏光显微镜及扫描电镜观察、X射线粉晶衍射、电子探针、红外光谱及紫外-可见光-近红外分光光度计等测试分析方法对绿色戈壁玛瑙的宝石矿物学特征及致色成因进行了深入研究。肉眼观察,阿拉善绿色玛瑙呈深绿色至褐绿色,微透明至不透明,相对密度、折射率、摩氏硬度等均符合石英质玉石的特点。偏光显微镜观察,绿鳞石富集于表层,并向内部呈放射状生长;方解石与石英均为隐晶质结构。扫描电镜观察,绿鳞石呈颗粒状分布于石英及方解石之间。X射线衍射分析结果表明,绿色戈壁玛瑙的物相组成主要为石英、方解石和绿鳞石。电子探针分析结果表明绿鳞石的主要化学组成为SiO₂、FeO、Al₂O₃、K₂O和MgO。红外光谱分析也显示存在绿鳞石对应基团的特征峰。表层绿鳞石在紫外-可见光-近红外分光光度计下显示出Fe²⁺与Fe³⁺的特征光谱,Fe²⁺与Fe³⁺之间的电荷转移是其...  相似文献   

刚果(金)马诺诺地区稀有金属矿床成矿地质特征与成矿规律          下载免费PDF全文

李继业  祝永平  柳长峰  祝艳  王纪昆  杨远东 《地质找矿论丛》2023,38(1):110-117

刚果(金)马诺诺地区地处基巴拉稀有金属成矿带,成矿地质条件优越。本文通过对该区稀有金属矿床成矿地质背景、典型矿床特征分析,总结了该区的成矿规律。结果表明,区域性断裂控制了该区的构造格局及矿产分布,具有明显的带状分布特征;岩浆活动强烈,其中尤以G4期岩浆侵入活动与稀有金属成矿关系密切;地层中的云母片岩类岩石提供良好的封闭条件,此3种要素的耦合有利于促使该区形成稀有金属矿床。  相似文献   

扬子陆块西缘中元古代晚期元谋花岗岩的时代、成因及构造意义          下载免费PDF全文

宋冬虎  王燕  刘兵  熊波  关奇  路永严  刘晓玮  刘军平  田素梅  米云川  张硕 《沉积与特提斯地质》2023,43(3):661-673

扬子陆块西缘晚中元古代地质演化史一直存在较大争议,本文选择以扬子西缘元谋杂岩中一套二长花岗岩为研究对象,开展岩相学、锆石U-Pb年代学、全岩地球化学等综合研究,为认识和理解扬子西缘晚中元古代地质演化提供支撑。两件元谋二长花岗岩样品的LA-ICP-MS锆石U-Pb年龄分别为1086±10 Ma（MSWD=1.4,n=50）和1099±10 Ma（MSWD=1.8,n=58）。所有样品具有高硅（SiO₂为69.44%~73.98%）、富碱（Na₂O+K₂O为6.11%~7.72%）、贫钙（CaO为0.39%~1.46%）、贫镁（MgO为0.52%~0.76%）、低钛（TiO₂为0.30%~0.59%）的特点,同时表现出强过铝质（A/CNK=1.19~1.35）及中钾钙碱性–钾玄岩系列特征。它们具有高的稀土元素总量（∑REE=211.60×10^-6~349.01×10^-6）,呈现轻稀土元素富集和重稀土元素亏损（（La/Yb）_N=4.32~7.36）;富集Rb、U、Th等大离子亲石元素和Zr、Th、Hf等,亏损Nb、Ta、Ba等元素,并具有明显的负Eu异常（δEu=0.46~0.59）,锆石饱和温度介于827~912℃之间,展示了A型花岗岩的属性。这些二长花岗岩可能是通过中上地壳的中酸性火成岩的部分熔融形成,结合前人的研究成果,它们最可能形成于弧后的伸展环境,综合扬子陆块周缘晚中元古代的岩浆记录,元谋杂岩中1.09 Ga二长花岗岩的形成应与扬子陆块开始参与Rodinia超大陆聚合有关。  相似文献   

Exploring the factors affecting urban ecological risk: A case from an Indian mega metropolitan region     

《地学前缘(英文版)》2023,14(1):101488

Assessment of ecological risk (ER) is a key approach to adapting and mitigating ecological deterioration in cities of developing countries. In developing countries, the ecological landscapes such as vegetation cover, water bodies, and wetlands are highly vulnerable due to rapid urban expansion. Therefore, urban ER (UER) assessment and its drivers are crucial to guide ecological protection as well as restoration. This study aims to explore the spatiotemporal pattern of UER and the impact of urban spatial form on UER in the Kolkata Megacity Region (KMR), India. This study developed a UER index and used spatial regression models across the urban centres. The ER has been assessed at city scale as well as grid-scale (2 km × 2 km and 5 km × 5 km) from 2000 to 2020. The results showed that ER has substantially increased over the last 20 years. The urban centres with very high and high ER substantially increased, i.e. from 21.95% in 2000 to 31.70% in 2020. Kolkata and its surrounding urban centres were mostly characterized by very high and high ER. ER was influenced by spatial variables (such as land use and landscapes pattern). However, remote sensing parameters were weakly related to ER. The spatial lag model (SLM) (R² = 0.8686) was found to be better fit model than spatial error model (SEM) (R² = 0.8661) and ordinary linear regression model (OLS) (R² = 0.8641). Thus, the findings of the study can improve research and a comprehensive framework for urban ecological resources and provide a scientific basis for urban ecosystem planning and restoration. In addition to this, it will guarantee the sustainable utilization of urban ecosystems.  相似文献   

Trace element and Nd isotope analyses of apatite in granitoids and metamorphosed granitoids from the eastern Central Asian Orogenic Belt: Implications for petrogenesis and post-magmatic alteration     

《地学前缘(英文版)》2023,14(2):101517

We present in situ trace element and Nd isotopic data of apatites from metamorphosed and metasomatized (i.e., altered) and unaltered granitoids in the Songnen and Jiamusi massifs in the eastern Central Asian Orogenic Belt, with the aim of fingerprinting granitoid petrogenesis, including both the magmatic and post-magmatic evolution processes. Apatites from altered granitoids (AG) and unaltered granitoids (UG) are characterized by distinct textures and geochemical compositions. Apatites from AG have irregular rim overgrowths and complex internal textures, along with low contents of rare earth elements (REEs), suggesting the re-precipitation of apatite during epidote crystallization and/or leaching of REEs from apatite by metasomatic fluids. ε_Nd(t) values of the these apatites are decoupled from zircon ε_Hf(t) values for most samples, which can be attributed to the higher mobility of Nd as compared to Sm in certain fluids. Apatites from UG are of igneous origin based on their homogeneous or concentric zoned textures and coupled Nd-Hf isotopic compositions. Trace element variations in igneous apatite are controlled primarily by the geochemical composition of the parental melt, fractional crystallization of other REE-bearing minerals, and changes in partition coefficients. Sr contents and Eu/Eu* values of apatites from UG correlate with whole-rock Sr and SiO₂ contents, highlighting the effects of plagioclase fractionation during magma evolution. Apatites from UG can be subdivided into four groups based on REE contents. Group 1 apatites have REE patterns similar to the host granitoids, but are slightly enriched in middle REEs, reflecting the influence of the parental melt composition and REE partitioning. Group 2 apatites exhibit strong light REE depletions, whereas Group 3 apatites are depleted in middle and heavy REEs, indicative of the crystallization of epidote-group minerals and hornblende before and/or during apatite crystallization, respectively. Group 4 apatites are depleted in heavy REEs, but enriched in Sr, which are features of adakites. Some unusual geochemical features of the apatites, including the REE patterns, Sr contents, Eu anomalies, and Nd isotopic compositions, indicate that inherited apatites are likely to retain the geochemical features of their parental magmas, and thus provide a record of small-scale crustal assimilation during magma evolution that is not evident from the whole-rock geochemistry.  相似文献   

Geochronology and geochemistry of lithium-rich tuffs in the Sichuan basin,western Yangtze: Implication for the magmatic origin and final closure of eastern Paleo-Tethys     

《地学前缘(英文版)》2023,14(1):101480

The felsic volcanogenic tuffs named “green-bean rocks” (GBRs), characterized by a green or yellowish green color, are widely distributed in the western Yangtze platform and have a high lithium content (286–957 ppm). This paper studies the ages, origin and tectonic setting of the GBRs in the Sichuan basin on the western margin of the Yangtze platform through the whole-rock geochemistry and zircon trace elements by using U–Pb dating and Hf–O isotopes. The GBR samples from the Quxian and Beibei sections yielded zircon U–Pb ages of 245.5 ± 1.8 Ma and 244.8 ± 2.2 Ma. These samples can be used as the isochronous stratigraphic marker of the Early–Middle Triassic boundary (EMTB) for regional correlation. The whole-rock and zircon geochemistry, and zircon Hf–O isotopes exhibited S-type geochemical affinities with high positive δ¹⁸O values (9.28‰–11.98‰), low negative ε_Hf(t) values (?13.87 to ? 6.79), and T_DM² ages of 2150–1703 Ma, indicating that the lithium-rich GBRs were generated by the remelting of the pre-existing ancient Paleoproterozoic layer without mantle source contamination in the arc-related/orogenic tectonic setting. The results of this study demonstrate that the lithium-rich GBRs in the western Yangtze platform were derived from arc volcanic eruptions along the Sanjiang orogen, triggered by the closure of the eastern Paleo-Tethys Ocean and the syn-collision between the continental Indochina and Yangtze blocks at ca. 247 Ma. This was marked by a major shift from I-type magmas with intermediate ε_Hf(t) values to S-type magmas with low negative ε_Hf(t) values. Collectively, our results provide new insights into the origin of the GBRs and decodes the closure of the eastern Paleo-Tethys.  相似文献   

Influence of underground space development mode on the groundwater flow field in Xiong’an new area          下载免费PDF全文

Yi-hang Gao  Jun-hui Shen  Lin Chen  Xiao Li  Shuang Jin  Zhen Ma  Qing-hua Meng 《地下水科学与工程》2023,11(1):68-80

The degree and scale of underground space development are growing with the continuous advancement of urbanization in China. The lack of research on the change of the groundwater flow field before and after the development of underground space has led to various problems in the process of underground space development and operation. This paper took the key development zone of the Xiong’an New Area as the study area, and used the Groundwater modeling system software (GMS) to analyse the influence on the groundwater flow field under the point, line, and surface development modes. The main results showed that the underground space development would lead to the expansion and deepening of the cone of depression in the aquifer. The groundwater level on the upstream face of the underground structure would rise, while the water level on the downstream face would drop. The “line” concurrent development has the least impact on the groundwater flow field, and the maximum rise of water level on the upstream side of the underground structure is expected to be approximately 3.05 m. The “surface” development has the greatest impact on the groundwater flow field, and the maximum rise of water level is expected to be 7.17 m.  相似文献   

开鲁盆地钱家店地区姚家组还原剂特征及铀成矿作用     

单芝波 《中国地质调查》2023,10(1):20-27

在开鲁盆地钱家店地区发现超大型铀矿床,为了界定储层还原剂对铀成矿作用的影响,通过岩心、镜下观察及相关测试技术的应用,进行了还原剂特征研究。结果表明: 研究区铀储层内部的还原剂主要以有机质-碳化植物碎屑、烃类、黄铁矿等形式为主。其中,有机质中常见的黄铁矿可以为铀成矿提供大量优质的还原剂; 矿化砂岩中甲烷含量及烃类总量较其他类型的砂岩高,并且随着铀的富集,气烃/重烃的比值明显升高,表明铀的富集与烃类也具有密切关系; 铀储层内部常见的黄铁矿类型包括莓球状黄铁矿、胶状黄铁矿、自形和它形黄铁矿,其作为还原剂以多种形式与铀共存。矿化层位的砂岩中,总有机碳(total organic carbon, TOC)含量与S_全含量普遍较高,而Fe₂O₃/FeO值则明显偏低; 与此相反,在非矿化层位的砂岩中,TOC含量与S_全含量普遍较低,而Fe₂O₃/FeO值较高,表明铀矿化与TOC、S_全含量具有一定的正相关关系,而与Fe₂O₃/FeO值呈负相关。对铀储层内部还原剂特征的深入研究,反映出还原剂对铀成矿作用的制约机理具有重要意义,为砂岩型铀矿的勘查预测提供理论指导。  相似文献   

渤海湾周缘高温地热异常特征及深部热结构分析     

张健  何雨蓓  姜程浩  褚伟  方桂 《地球学报》2023,44(1):57-69

渤海湾周缘高温地热异常区是华北重要的地热资源区,研究其浅层高温地热异常及深层高温地热结构,是解决中国东部高温地热勘查开发瓶颈的重要基础,对加快构建东部现代能源体系、推进“双碳”目标进程具有重要的科学意义。利用最新的中国大陆岩石圈速度模型USTClitho2.0和航磁资料,在大地热流资料约束下,本文计算了渤海湾周缘浅层与深层高温热结构,结果表明:该区居里面平均深度20.8km,居里温度420℃,中、上地壳高温热结构与居里面起伏形态密切相关。上地壳生热率随深度增大而递减,反映了放射性生热元素向上迁移、在浅层富集的垂向分异特征。Moho面温度在600～800℃之间,岩石圈底界面1300℃等温面深度在66.3～97.5 km之间,平均值为76.8 km。依据USTClitho2.0模型Vp、Vs速度结构,本文修正了前人的地壳分层结构及上地壳生热率,计算了研究区内全部91个大地热流点的壳幔热流比,结果表明:Qc/Q=56.4%、Qm/Q=43.6%, Qc/Q>Qm/Q,显示该区为“热壳”结构。前人认为此区是“冷壳热幔”型热结构,本文的计算结果修正了前人的认识,指出上地壳层热流在地表总热流...  相似文献